کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176436 | 458943 | 2013 | 8 صفحه PDF | دانلود رایگان |

• We synthesized two rhodamine–pyrene conjugated ratiometric chemosensors.
• The two sensors were differentiated by a spirothiolactone and a spirolactone unit.
• With Hg2+, the spirothiolactone sensor exhibited a weakened FRET behavior.
• The spirolactone sensor was hydrolyzed inducing a monomer–excimer switch with Hg2+.
• Both sensors exhibited colorimetric and fluorescent dual-responses toward Hg2+.
Two novel rhodamine–pyrene conjugated chemosensors were successfully designed and synthesized, which exhibited high affinity to Hg2+ ions. As ratiometric chemosensors, each displayed highly selective and sensitive colorimetric and fluorogenic dual-responses toward Hg2+. The comparison of two chemosensors indicated that the spirothiolactone containing sensor was superior to the spirolactone analog in sensing behavior when detecting Hg2+, presumably due to the thiophilic nature of mercury and the different sensing mechanisms in operation. Upon interaction with Hg2+, the spirothiolactone showed a 1:1 stoichiometry for the Hg2+ complex, accompanied with a weakened fluorescence resonance energy transfer (FRET) behavior. However, the spirolactone was hydrolyzed and consequently induced the monomer–excimer switch of the resulted pyrene in the presence of Hg2+ ions.
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Journal: Dyes and Pigments - Volume 98, Issue 3, September 2013, Pages 339–346