High vertical resolution water vapour profiles in the upper troposphere and lower stratosphere retrieved from MAESTRO solar occultation spectra

An algorithm has been developed that retrieves water vapour profiles in the upper troposphere and lower stratosphere from optical depth spectra obtained by the Measurements of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (MAESTRO) instrument onboard the SCISAT satellite as part of the Atmospheric Chemistry Experiment (ACE) mission. The retrieval relies on ro-vibrational absorption of solar radiation by water vapour in the 926–970 nm range. During the iterative inversion process, the optical depth spectra are simulated at the spectral resolution and sampling frequency of MAESTRO using the correlated-k approximation. The Chahine inversion updates the water vapour volume mixing ratio (VMR), adjusting all retrieval layers simultaneously, to match the observed differential optical depth due to absorption by water vapour and ozone at each tangent height. This approach accounts for significant line saturation effects. Profiles are typically obtained from ∼22 km down to the cloud tops or to 5 km, with relative precision as small as 3% in the troposphere. In the lower stratosphere, the precision on water vapour VMR is ∼1.3 μmol/mol in an individual retrieval layer (∼1 km thick). The spectral capability of MAESTRO allows for the clear separation of extinction due to water vapour and aerosol, and for the fitting quality to be quantified and used to determine an altitude-dependent convergence criterion for the retrieval. In the middle troposphere, interhemispheric differences in water vapour VMR are driven by oceanic evaporation whereas in the upper troposphere, deep convection dominates and a strong seasonal cycle is observed at high latitudes.