کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176942 | 458960 | 2012 | 5 صفحه PDF | دانلود رایگان |
A linear cyanine dye (LDP) guest comprising two binding sites, one 4-[2-[4-(dimethylamino)phenyl]ethenyl]pyridinium group and one p-aminophenoxy ethylene group, was synthesized and proved could form inclusion complexes with cucurbit[7]uril (CB[7]) in aqueous solution. A partially encapsulated ([2]pseudorotaxane) state in which one CB[7] ring moved fast between the two binding sites was originally detected and was then transferred into a full encapsulated ([3]pseudorotaxane) state where two CB[7] macrocycles resided on both binding sites with the continuously adding of CB[7] to LDP. The two binding constants K1 and K2 were determined as (6.29 ± 0.88) × 104 M−1 and (1.58 ± 0.17) × 104 M−1, respectively. Compared with the free LDP, the photostability of the [3]pseudorotaxane is found been distinctively promoted, while that of the [2]pseudorotaxane state is hardly improved.
► A linear cyanine dye LDP containing two Cucurbituril recognition sites was synthesized.
► One [2]pseudorotaxane and one [3]pseudorotaxane states were found when mixing LDP and CB[7] in aqueous solution.
► The photostability of LDP was distinctly improved in the [3]pseudorotaxane state.
Journal: Dyes and Pigments - Volume 94, Issue 2, August 2012, Pages 266–270