Crystal structure, dielectric and piezoelectric properties of Ta/W codoped Bi3TiNbO9 Aurivillius phase ceramics

• Ta/W codoped BTN ceramics were prepared by the mixed oxides route.
• Curie temperature is correlated with the lattice distortion influenced by the Ta/W additives.
• Ta/W acted as donor doping and decreased of the number of holes and/or oxygen vacancies.
• Piezoelectric coefficient was significantly increased by Ta/W multiple dopants.
• BTTNW-2 ceramics were indeed piezoelectric in nature at 600 °C.

Aurivillius phase Bi3Ti1−xTaxNb1−xWxO12 high temperature piezoceramics were prepared by a conventional solid state reaction method. The crystal structure, dielectric, electrical conduction and piezoelectric properties were systematically studied. Pure or modified Bi3TiNbO9 ceramics revealed the presence of only two-layered Aurivillius phase, indicating that Ta/W doping entered into the B-site of pseudo-perovskite structure and formed solid solutions. The Curie temperature had a strong reliance on the structural distortion. Furthermore, Ta/W dopants act as a donor doping, decrease the number of oxygen vacancies and facilitate the domain wall motion. As a result, Ta/W modifications significantly increase the DC resistivity and piezoelectric properties. Bi3Ti0.98Ta0.02Nb0.98W0.02O12 ceramics possess the optimum d33 value (∼12.5 pC/N) together with a high TC point (∼893 °C). Moreover, the resonance–antiresonance spectra demonstrate that the Ta/W-BTN ceramics are indeed piezoelectric in nature at 600 °C. The d33 value of BTTNW-2 ceramic remains ∼12.2 pC/N after annealing at 700 °C. These factors suggest that the BTTNW-based ceramic is a promising candidate for ultra-high temperature sensor applications.