کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
178724 | 459315 | 2016 | 5 صفحه PDF | دانلود رایگان |
• Electrochemical technologies as synthetic routes of poly(vinylpyrrolidone) (PVP) nanogels
• Electro-oxidation (EO) and electro-Fenton (EF) as simpler and cheaper methods
• Good perspectives for EF with continuous H2O2 electrogeneration and Fe2 + regeneration
• Smaller hydrodynamic radius and lower polydispersity index of PVP in EF process
• Proof of concept for further work with microfluidic reactors to enhance biomedical suitability
A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2 + regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone).
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Journal: Electrochemistry Communications - Volume 62, January 2016, Pages 64–68