Synthesis and characterization of Pb(Zr0.5Ti0.5)O3 nanofibers

Pb(Zr0.5Ti0.5)O3 (PZT) piezoelectric ceramic fibers were prepared by using electrospun PZT/poly(vinyl acetate) (PVAc) composite fibers by calcination for 1 h at the temperature range of 500 °C–700 °C in air. The morphology and crystal structure of calcined PZT nanofibers were characterized as a function of calcination temperature with an aid of XRD, FT-IR, SEM, and TEM. XRD and FT-IR results revealed that pyrochlore phase began to appear after calcination at 500 °C. For the fibers calcined at 550–600 °C, the dominant phase of tetragonal perovskite PZT with a weak pyrochlore phase was detected. The pyrochlore and tetragonal perovskite phases coexisted for the fibers calcined at 650–700 °C. The morphology of the fibers has changed from a smooth and uniform fiber to a porous fiber with increasing the temperature. The optimized fibers with a diameter of 334 nm were obtained when the fibers were calcined at 550 °C.

► Synthesis of Pb(Zr0.5Ti0.5)O3 (PZT) piezoelectric ceramic fibers by using electrospun PZT/poly(vinyl acetate) composite fibers by calcination for 1 h at the temperature range of 500 °C–700 °C in air.
► Onset of pyrochlore phase after calcination at 500 °C.
► The dominant phase of tetragonal perovskite PZT with a weak pyrochlore phase for the fibers calcined at 550–600 °C.
► The pyrochlore and tetragonal perovskite phases at 650–700 °C.