کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1788925 | 1023483 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Flow injection determination of catechol based on polypyrrole-carbon nanotube-tyrosinase biocomposite detector
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
A flow injection catechol biosensor based on tyrosinase entrapped in carbon nanotube modified polypyrrole biocomposite film on a glassy carbon surface has been developed. Amperometric response was measured as a function of concentration of catechol, at a fixed bias voltage of â50 mV at a flow rate of 1 mL/min. The proposed biosensor exhibited impressive analytical performance such as a linear range between 3 and 50 μM, a short response time (10 s), a detection limit of 0.671 μM and an excellent operational (with a relative standard deviation of 0.54%) and long-term stability (85% remained after 10th week). A comparison of the analytical parameters of the developed biosensor with polypyrrole/tyrosinase film electrode was performed in the study. CNT was shown to enhance the electron transfer between the electrode and enzyme and capable to carry higher bioactivity owing to its intensified surface area.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Applied Physics - Volume 10, Issue 1, January 2010, Pages 323-328
Journal: Current Applied Physics - Volume 10, Issue 1, January 2010, Pages 323-328
نویسندگان
Seyda Korkut Ozoner, Mevra Yalvac, Elif Erhan,