کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1789146 1023494 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Photophysical and electrochemical properties of D–π–A type solvatofluorchromic isophorone dye for pH molecular switch
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Photophysical and electrochemical properties of D–π–A type solvatofluorchromic isophorone dye for pH molecular switch
چکیده انگلیسی

The photophysical and electrochemical properties of a donor-π-accepter (D–π–A) type isophorone dye, 2-(3-(4-((2-hydroxyethyl)(methyl)amino)styryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile with asymmetrical structure, was investigated. It showed interestingly solvatofluorchromic property in various solvents based on intramolecular charge transfer mechanism. Its LUMO and HOMO values were obtained by electrochemical measurement and theoretical calculation. In addition, it can be also constructed a pH fluorescent molecular switch by modulation of intramolecular charge transfer with protonation/deprotonation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Applied Physics - Volume 9, Issue 4, July 2009, Pages 783–787
نویسندگان
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