کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1800053 1524875 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Infrared spectroscopic and electron paramagnetic resonance studies on Dy substituted magnesium ferrite
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Infrared spectroscopic and electron paramagnetic resonance studies on Dy substituted magnesium ferrite
چکیده انگلیسی


• Absorption bands between 400 and 1000 cm−1 reveal the formation of spinel phase.
• The force constant on tetrahedral and octahedral site is used to explain the bond length.
• Electron paramagnetic resonance spectra exhibit broad, asymmetric resonance peaks.
• Spin frustration in spinel ferrites is explained by the broadening of line width.

Dysprosium substituted magnesium ferrite with composition MgDyxFe2−xO4 with 0.00≤x≤0.07 synthesized by the solid state reaction technique was subjected to Fourier transform infrared spectroscopy and electron paramagnetic resonance studies. Infrared spectrum analysis were carried out to confirm the spinel phase formation and to ascertain the cation distribution in the ferrite phase. The absorption spectra show two significant absorption bands between 400 and 1000 cm−1 which are attributed to tetrahedral (A) and octahedral (B) sites of the spinel phase. The positions of bands were found to be composition dependent. Splitting of bands as well as appearance of shoulders shows the presence of Fe2+ ions in the system. The force constants for tetrahedral and octahedral sites were calculated and found to vary with Dy3+ ions content. Electron paramagnetic resonance spectra of these samples exhibit broad, asymmetric resonance signal due to Fe3+/Dy3+ ions present in the host lattice. The spectra become broader with Dy3+ ions substitution in pure Mg-ferrite and this broadening is attributed to surface spin disorder (spin frustration) possibly coming from mainly antiferromagnetic interactions between the neighbouring spins in the magnetic grains. The weak superexchange interactions results in the broadening of the resonance line width and large g-value as compared to the free electron value.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 345, November 2013, Pages 255–260
نویسندگان
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