Effects of solvent polarity on mutual styrene grafting onto polypropylene by electron beam irradiation

Radiation induced mutual grafting of styrene onto polypropylene has been carried using several grafting solutions with different organic solvents and polarity levels. In the mixture of styrene and protic polar solvents high grafting yields were obtained. This behavior suggests that grafting process does not have dependence on swelling of the substrate, something that is expected when a non-polar substrate and a non-polar media are in contact. In this case, the grafting yield may be related to the free radical generation at protic polar solvent; these reactive specimens start the reaction on substrate surface to allow the accessibility of monomer species to active sites. Some reaction mechanisms are proposed.

► Styrene grafting is performed with high yield when protic polar solvents are used.
► Results are related to effects from electron solvation and dipole interactions.
► Grafting samples performed in n-octanol mixtures had crystallinity changes.