Ultraviolet-radiation-curing of an organically modified silicate-based material system with epoxy functionality, and the role of titanium

► Sol-gel synthesis method for an ORMOSIL material system described successfully. ► So-synthesised system processed with UV-irradiation. ► Structural, thermal, and mechanical properties characterised. ► Effects of synthesis/process parameters, in particular UV dose and Ti content identified comparatively. ► Potential suitability of this material system for use in dental restoration demonstrated.