کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1891520 1533542 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Interaction of aromatic alcohols, aldehydes and acids with α-hydroxyl-containing carbon-centered radicals: A steady state radiolysis study
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم تشعشع
پیش نمایش صفحه اول مقاله
Interaction of aromatic alcohols, aldehydes and acids with α-hydroxyl-containing carbon-centered radicals: A steady state radiolysis study
چکیده انگلیسی

Benzaldehyde and its derivatives efficaciously oxidize in aqueous solutions α-hydroxyl-containing carbon-centered radicals (α-HCR) of various structures, suppressing thereby the radical recombination and fragmentation reactions. The compounds containing cinnamic moieties are capable of adding α-hydroxyethyl radicals (α-HER) to the carbon–carbon double bonds conjugated with the aromatic system to form molecular products identifiable by mass spectrometry. On radiolysis of aqueous ethanol solutions, reduction of α-HER by aromatic alcohols and acids has been shown to proceed via formation of their adducts with hydrated electron species.


► Benzaldehydes oxidize α-hydroxyl-containing carbon-centered radicals.
► Phenylproranoids add α-hydroxyethyl radicals to the activated C=C bonds.
► Aromatic alcohols and acids form radical-adducts with eaq− in aqueous solutions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Radiation Physics and Chemistry - Volume 82, January 2013, Pages 35–43
نویسندگان
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