کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1891520 | 1533542 | 2013 | 9 صفحه PDF | دانلود رایگان |

Benzaldehyde and its derivatives efficaciously oxidize in aqueous solutions α-hydroxyl-containing carbon-centered radicals (α-HCR) of various structures, suppressing thereby the radical recombination and fragmentation reactions. The compounds containing cinnamic moieties are capable of adding α-hydroxyethyl radicals (α-HER) to the carbon–carbon double bonds conjugated with the aromatic system to form molecular products identifiable by mass spectrometry. On radiolysis of aqueous ethanol solutions, reduction of α-HER by aromatic alcohols and acids has been shown to proceed via formation of their adducts with hydrated electron species.
► Benzaldehydes oxidize α-hydroxyl-containing carbon-centered radicals.
► Phenylproranoids add α-hydroxyethyl radicals to the activated C=C bonds.
► Aromatic alcohols and acids form radical-adducts with eaq− in aqueous solutions.
Journal: Radiation Physics and Chemistry - Volume 82, January 2013, Pages 35–43