کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1892232 1043959 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The ultraviolet spectrum of condensed methylamine at 25 K
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم تشعشع
پیش نمایش صفحه اول مقاله
The ultraviolet spectrum of condensed methylamine at 25 K
چکیده انگلیسی

Using a monochromated synchrotron light source we have recorded the VUV spectrum of a film of solid methylamine, CH3NH2, from 6 to 10 eV. The solid-phase spectrum differs substantially from the gas-phase spectra with lower lying Rydberg states in the gas phase being absent in the solid phase. Vibrational structure visible in the gas phase is also absent in the solid phase. We suggest hydrogen bonding in solid CH3NH2 hinders the ν9 NH2 umbrella mode seen in the gas phase, instead a series of progressions in ν6 (CH3 umbrella) is observed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Radiation Physics and Chemistry - Volume 76, Issue 5, May 2007, Pages 745–749
نویسندگان
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