کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1892240 1043959 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of diluent on radiolysis of amides in organic solution
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم تشعشع
پیش نمایش صفحه اول مقاله
Influence of diluent on radiolysis of amides in organic solution
چکیده انگلیسی

The radiolytic behavior of N,N,N′,N′-tetraoctyldiglycolamide, N,N′-dimethyl-N,N′-dioctyl-2-(3′-oxapentadecyl)malonamide, and N,N-dioctylhexanamide in n-dodecane was investigated by irradiation with γ-rays and electron pulses. The results showed n-dodecane has a sensitization effect on the radiolysis of these amides, owing mainly to a charge transfer from radical cations of n-dodecane to the amide molecules in the primary process observed in pulse radiolysis. This result was supported by the difference in the ionization potentials between n-dodecane and these amides.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Radiation Physics and Chemistry - Volume 76, Issue 5, May 2007, Pages 794–800
نویسندگان
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