کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
205649 | 461121 | 2015 | 8 صفحه PDF | دانلود رایگان |
• The Guiding and Heshan coals are characterized by superhigh-organic-sulfur (SHOS).
• The SHOS coals have highly-elevated concentrations of V, Cr, Se, Mo, Cd, Re, and U.
• V, Cr, Se, Re, U, and Mo in these SHOS coals are mainly associated with organic matter.
• Cadmium is mainly distributed in sulfide minerals.
• A proportion of Re is associated carbonate fraction.
The concentrations and modes of occurrence of highly-elevated trace elements including V, Cr, Se, Mo, Cd, Re, and U in some late Permian coals preserved within marine carbonate successions from Southwest China, were investigated using inductively coupled-plasma mass spectrometry (ICP-MS), sequential chemical extraction procedures (SCEP), field emission-scanning electron microscopy in conjunction with an energy-dispersive X-ray spectrometer (FE SEM–EDS), and X-ray powder diffraction analysis (XRD). The coals present in this study are characterized by superhigh-organic-sulfur, ranging from 5.01% to 9.87%, and by highly-elevated concentrations of V (859 ppm on average), Cr (370 ppm), Se (29.3 ppm), Mo (364 ppm), Cd (3.87 ppm), Re (0.47 ppm), and U (214 ppm). The minerals in the coals are predominantly composed of illite or mixed-layer illite/smectite, which, together with quartz, were derived from sediment-source region. The SCEP results showed that elements V, Cr, Se, Re, U, and Mo are mainly associated with organic matter of the coal, and to a lesser extent, are associated with illite or mixed-layer illite/smectite. Traces of U-bearing minerals (coffinite and brannerite) were identified in the coal. Cadmium is mainly and Cr and Mo are partially distributed in sulfide minerals. A significant proportion of Re is also associated with the carbonate fraction.
Journal: Fuel - Volume 156, 15 September 2015, Pages 190–197