کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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207580 | 461220 | 2010 | 8 صفحه PDF | دانلود رایگان |

Wax deposition is a well known flow assurance risk in crude oil production due to temperature decrease which depends mainly on the crude oil nature and the type and content of paraffin. The prevention of this problem requires a detailed characterization of the crude oil and the availability of reliable predictive models.The experimental determination and quantification of the precipitation process is quite complex and time consuming and simpler techniques are of interest to carry out such study. Among them, differential scanning calorimetry (DSC) technique is appropriate to develop routine essays and has been extensively applied to determine wax appearance temperature in crude oil and fractions because the simplicity and fast response of the technique.However, the determination of wax precipitation curve from a quantitative DSC interpretation is usually based on pure n-alkane properties and involves some difficulties. In this work, a new procedure has been developed including the effect of the fluid composition on the precipitation temperature and the melting heat. Solid–liquid equilibrium equations were introduced through a simplified thermodynamic model in the integration procedure resulting in an iterative method combining experimental and calculated values. The final method yields the wax appearance temperature (WAT), the full wax precipitation curve and the estimated wax composition.In order to validate the procedure, several crude oil fractions were used as standards due to the advantage of a narrow n-alkane distribution. Experimental characterization for the cloud point temperature, the n-alkane distribution (determined by gas chromatography with mass detector, GCMS) and DSC was carried out. The agreement between experimental results and those obtained from the DSC interpretation is a good check for the proposed procedure.
Journal: Fuel - Volume 89, Issue 5, May 2010, Pages 1087–1094