کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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231060 | 1427412 | 2012 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: In situ Raman spectroscopy for the evaluation of solubility in supercritical carbon dioxide mixtures In situ Raman spectroscopy for the evaluation of solubility in supercritical carbon dioxide mixtures](/preview/png/231060.png)
Solubility phenomena in supercritical carbon dioxide (SC-CO2) mixtures have been studied in situ using Raman spectroscopy. A Raman spectroscopy instrumentation has been linked to a high-pressure optical cell. The set-up was tested in the system SC-CO2/alkyl ketene dimer (AKD) under pressures up to 300 bars and temperatures up to 80 °C. As a proof of concept, the possibility to study solubility of AKD in SC-CO2 as well as solubility of SC-CO2 in AKD by studying the Raman signal of SC-CO2 has been presented. Statistically tested results show how these competitive phenomena depend on the density region of the SC-CO2. Raman spectra of AKD in the system AKD/SC-CO2 have also been acquired, demonstrating the prospect of quantitative analysis for solubility studies in SC-CO2. Furthermore, this versatile set-up provides information about thermal expansion of the vessel and evidences the need for corrected equations in this commonly used region of pressures and temperatures.
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► Solubility of supercritical CO2 in alkyl ketene dimer and vice versa is studied by Raman spectroscopy.
► Statistically treated results show competitive solubility phenomena dependent on CO2 density.
► Possibility of quantitative in situ solubility studies using Raman is outlined.
► Thermal expansion of the vessel is evidence by Raman spectroscopy.
► Ruby-fluorescence signal measures the temperature inside the high-pressure cell.
Journal: The Journal of Supercritical Fluids - Volume 65, May 2012, Pages 87–92