کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
231986 1427449 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of polymer properties on poly(vinylidene fluoride) particles produced by rapid expansion of CO2 + polymer mixtures
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Effect of polymer properties on poly(vinylidene fluoride) particles produced by rapid expansion of CO2 + polymer mixtures
چکیده انگلیسی

The generation of nanoscale primary poly(vinylidene fluoride) (PVDF) particles by rapid expansion of supercritical solutions (RESS) is reported. The experimental results show that RESS enables the formation of PVDF particles with median particle diameters ranging from 56 to 226 nm and that the size of PVDF particles can be influenced by polymer properties. The particle size can be decreased either by increasing molar mass, in case of identical polymer end groups, or by increasing the degree of crystallinity, in case of similar molar mass and different end groups.

Influence of polymer molar mass and end group on PVDF particle sizes obtained from RESS experiments performed at TE = 323 K, p0 = pE = 20 MPa and T0 = 333 K.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Supercritical Fluids - Volume 48, Issue 1, February 2009, Pages 48–55
نویسندگان
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