کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
231986 | 1427449 | 2009 | 8 صفحه PDF | دانلود رایگان |

The generation of nanoscale primary poly(vinylidene fluoride) (PVDF) particles by rapid expansion of supercritical solutions (RESS) is reported. The experimental results show that RESS enables the formation of PVDF particles with median particle diameters ranging from 56 to 226 nm and that the size of PVDF particles can be influenced by polymer properties. The particle size can be decreased either by increasing molar mass, in case of identical polymer end groups, or by increasing the degree of crystallinity, in case of similar molar mass and different end groups.
Influence of polymer molar mass and end group on PVDF particle sizes obtained from RESS experiments performed at TE = 323 K, p0 = pE = 20 MPa and T0 = 333 K.Figure optionsDownload as PowerPoint slide
Journal: The Journal of Supercritical Fluids - Volume 48, Issue 1, February 2009, Pages 48–55