Synthesis of novel CuS with hierarchical structures and its application in lithium-ion batteries

Novel sphere-like CuS hierarchical structures are fabricated by solvothermal approach without any surfactant and template. SEM and TEM characterizations show that the CuS sphere-like structures are composed of tens to hundreds of well-arranged and self-assembled nanoplates with a thickness of about 20 nm. The effects of dosage of CuCl2
• 6H2O, temperature and reaction time on the morphology of the products are systematically investigated and the results indicate that the CuS sphere-like hierarchical structures can only be obtained under certain experimental conditions. The possible formation mechanism of the CuS hierarchical structures is proposed. In addition, the possibility of using CuS as the electrode material for lithium ion batteries is studied.

Novel CuS hierarchical structures fabricated by solvothermal approach without any surfactant and template are composed of dozens of well-arranged and self-assembled nanoplates with a thickness of about 20 nm. The factors in the morphology of the products are systematically investigated and it is found that CuS sphere-like hierarchical structures can only be obtained under certain experimental conditions.Figure optionsDownload as PowerPoint slideResearch highlights
► The solvothermal method used in the experiment is simple and reliable. Besides, any surfactant and template is not used.
► The CuS sphere-like hierarchical structure is self-assembled and novel.
► On the basis of the SEM images, a reasonable mechanism for the formation of the CuS hierarchical structure is proposed.
► The characterization of the as-obtained CuS as electrode material in lithium-ion batteries is preliminarily investigated.