کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
239244 465807 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of LiFePO4/(Ag + C) composite cathodes with nano-carbon webs
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and characterization of LiFePO4/(Ag + C) composite cathodes with nano-carbon webs
چکیده انگلیسی

LiFePO4/(Ag + C) composite cathodes with a new type of nano-sized carbon webs were synthesized by two methods of an aqueous co-precipitation and a sol–gel process, respectively. Simultaneous thermogravimetric-differential thermal analysis indicates that the crystallization temperature of LiFePO4 is about 455–466 °C, which is close to the pyrolysis temperature of polypropylene, 460 °C. The silver and carbon co-modifying does not affect the olivine structure of LiFePO4 but improves its kinetics in terms of discharge capacity and rate capability. Discharge capacities were improved from 153.4 mA h g− 1 of LiFePO4/C to 160.5 mA h g− 1and 162.1 mA h g− 1 for LiFePO4/(Ag + C) cathodes synthesized by the co-precipitation and sol–gel methods, respectively. The possible reasons for the small difference in discharge capacity of two LiFePO4/(Ag + C) cathodes were discussed. AC impedance measurements show that the Ag + C co-modification decreases the charge transfer resistance of LiFePO4/(Ag + C) cathodes.

Some morphology like nano-webs in the light grey region was found around the particles (marked with arrows in the above TEM image). The light grey region is carbon, which may reside on the interfaces between LiFePO4 particles, and/or exist in the interior part of the particle, and/or wrap on the particle surfaces.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Powder Technology - Volume 181, Issue 3, 12 February 2008, Pages 301–306
نویسندگان
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