Effects of post-mercury-control fly ash on fresh and hardened concrete properties

Activated carbon injection is the most mature technology for mercury capture from coal burning power plants; however, this technology increases the carbon content and mercury concentration in the fly ash. This, in turn, may reduce the suitability of fly ash for use in concrete and call into question the safety of using fly ash derived from this process. The focus of this paper is to investigate the reuse potential of post-mercury-control fly ash in concrete by examining the influence of three fly ashes derived from the activated carbon injection on the air content, compressive strength, permeability, and resistance to freezing and thawing of concrete mixtures. Laboratory testing confirmed the influence of the carbon on the air content of the concrete. However there was no difficulty in entraining air in activated carbon injection fly ash concretes within the recommended dosage range of the air-entraining admixture. All air-entrained fly ash concretes exhibited excellent characteristics in compressive strength (⩾32.0 MPa, 4641 psi at 28 days), resistance to chloride-ion penetration (moderate to low at 28 days of age) and freeze–thaw (⩾90 average durability factor after 300 cycles). The possible leaching of toxic elements including mercury from one fly ash sample used in this study was also evaluated using the US Environmental Protection Agency’s Toxicity Characteristic Leaching Procedure. The test results indicated that the leaching of toxic elements was much lower than the contamination level.

► No difficulty in entraining air in the ACI fly ash concretes using AEA.
► Influence of the carbon on the air content of the concrete was confirmed.
► ACI fly ash concretes exhibited excellent hardened concrete properties.
► The leaching of toxic elements was much lower than the contamination level by TCLP.