کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
260640 503667 2009 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chloride binding of cement-based materials subjected to external chloride environment – A review
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی عمران و سازه
پیش نمایش صفحه اول مقاله
Chloride binding of cement-based materials subjected to external chloride environment – A review
چکیده انگلیسی

This paper reviews the chloride binding of cement-based materials subjected to external chloride environments. Chloride ion exist either in the pore solution, chemically bound to the hydration products, or physically held to the surface of the hydration products. Chloride binding of cement-based material is very complicated and influenced by many factors, such as chloride concentration, cement composition, hydroxyl concentration, cation of chloride salt, temperature, supplementary cementing materials, carbonation, sulfate ions and electrical field etc. Four different types of binding isotherms, namely linear, Langmuir, Freundlich and BET binding isotherm have been proposed to describe the relationship between free and bound chloride, none of which can accurately express the relationships between free and bound chloride within the whole concentration range. Freundlich binding isotherm seems to be the most approximate one. However, some field data fit linear isotherm well. This may be ascribed to the leakage of hydroxyl ion. Many service life prediction models based on diffusion mechanism alone have been proposed during the past two decades. If chloride ion binding is not considered in the models, it underestimates the predicated service life.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Construction and Building Materials - Volume 23, Issue 1, January 2009, Pages 1–13
نویسندگان
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