Synergistic effect of helium and hydrogen for bubble swelling in reduced-activation ferritic/martensitic steel under sequential helium and hydrogen irradiation at different temperatures

• Helium/hydrogen synergistic effect can increase irradiation swelling of RAFM steel.
• Hydrogen can be trapped to the outer surface of helium bubbles.
• Too large a helium bubble can become movable.
• Point defects would become mobile and annihilate at dislocations at high temperature.
• The peak swelling temperature for RAFM steel is 450 °C.

In order to investigate the synergistic effect of helium and hydrogen on swelling in reduced-activation ferritic/martensitic (RAFM) steel, specimens were separately irradiated by single He+ beam and sequential He+ and H+ beams at different temperatures from 250 to 650 °C. Transmission electron microscope observation showed that implantation of hydrogen into the specimens pre-irradiated by helium can result in obvious enhancement of bubble size and swelling rate which can be regarded as a consequence of hydrogen being trapped by helium bubbles. But when temperature increased, Ostwald ripening mechanism would become dominant, besides, too large a bubble could become mobile and swallow many tiny bubbles on their way moving, reducing bubble number density. And these effects were most remarkable at 450 °C which was the peak bubble swelling temperature for RAMF steel. When temperature was high enough, say above 450, point defects would become mobile and annihilate at dislocations or surface. As a consequence, helium could no longer effectively diffuse and clustering in materials and bubble formation was suppressed. When temperature was above 500, helium bubbles would become unstable and decompose or migrate out of surface. Finally no bubble was observed at 650 °C.