Application of PHADEC method for the decontamination of radioactive steam piping components of Caorso plant

• Application of PHADEC chemical off-line methodology.
• Decontamination of radioactive steam piping components of Caorso turbine building.
• Experimental characterization of metallic components, e.g., by SEM analysis.
• Measure of the efficiency of treatment by means of the reduction of activity and vs. the treatment time.
• Minimization of secondary waste produced during decontamination activity of Caorso BWR plant.

The dismantling of nuclear plants is a complex activity that originates often a large quantity of radioactive contaminated residue.In this paper the attention was focused on the PHADEC (PHosphoric Acid DEContamination) plant adopted for the clearance of Caorso NPP (in Italy) metallic systems and components contaminated by Co60 (produced by the neutron capture in the iron materials), like the main steam lines, moisture separator of the turbine buildings, etc.The PHADEC plant consists in a chemical off line treatment: the crud, deposited along the steam piping during life plant as an example, is removed by means of acid attacks in ponds coupled to a high pressure water washing.Due to the fact that the removed contaminated layers, essentially, iron oxides of various chemical composition, depend on components geometry, type of contamination and time of treatment in the PHADEC plant, it becomes of meaningful importance to suggest a procedure capable to improve the control of the PHADEC process parameters.This study aimed thus at the prediction and optimization of the mentioned treatment time in order to improve the efficiency of the plant itself and to achieve, in turn, the minimization of produced wastes. To the purpose an experimental campaign was carried out by analysing several samples, i.e., taken along the main steam piping line.Smear tests as well as metallographic analyses were carried out in order to determine respectively the radioactivity distribution and the crud composition on the inner surface of the components. Moreover the radioactivity in the crud thickness was measured. These values allowed finally to correlate the residence time in the acid attack ponds to the level of the achieved decontamination.