Studies on surface impregnation combustion method to prepare supported Co/SiO2 catalysts and its application for Fischer–Tropsch synthesis

A series of supported Co/SiO2 catalysts were prepared by surface impregnation combustion method using cobalt nitrates and citric acid, and the precursors were burnt in different atmospheres. The effects of different calcination atmospheres on the properties of the supported Co/SiO2 catalysts were systemically studied by TG-DTA, XRD, Raman spectrum, TPR, in situ FTIR, TEM, BET and H2-chemisorption techniques. The burnt catalyst Cargon-air-reduction which was first burnt in argon and then oxidized in air had about 10 nm Co3O4 crystalline size, much smaller than that which was directly burnt in air (Co3O4 size: about 15 nm) and that prepared by conventional impregnation method (Co3O4 size: about 32 nm) using cobalt nitrate as impregnating solution. Characterizations and FTS results of two other references using different organic cobalt salt aqueous (cobalt acetate and cobalt citrate) as impregnating solution were also added in the supporting information. Comparing with our previously reported Cargon catalyst directly burnt in the argon atmosphere without further reduction, the influence from surface amorphous carbon and carbonic residues was completely eliminated. The activity of the burnt catalyst Cargon-air-reduction prepared by surface impregnation method was threefold higher than that of the reference CN-reduction prepared by conventional incipient-wetness impregnation method. The surface impregnation combustion method described herein was promising to prepare highly dispersed supported metallic catalysts with smaller particle sizes.

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► Highly dispersed Co/SiO2 catalysts were prepared by surface impregnation combustion method.
► Co3O4 crystalline sizes of the as-prepared catalysts were only about 10 nm.
► The activity of the as-prepared catalysts for FTS was higher.