Spatial patterns and temporal trends in mercury concentrations, precipitation depths, and mercury wet deposition in the North American Great Lakes region, 2002–2008

Annual and weekly mercury (Hg) concentrations, precipitation depths, and Hg wet deposition in the Great Lakes region were analyzed by using data from 5 monitoring networks in the USA and Canada for a 2002–2008 study period. High-resolution maps of calculated annual data, 7-year mean data, and net interannual change for the study period were prepared to assess spatial patterns. Areas with 7-year mean annual Hg concentrations higher than the 12 ng per liter water-quality criterion were mapped in 4 states. Temporal trends in measured weekly data were determined statistically. Monitoring sites with significant 7-year trends in weekly Hg wet deposition were spatially separated and were not sites with trends in weekly Hg concentration. During 2002–2008, Hg wet deposition was found to be unchanged in the Great Lakes region and its subregions. Any small decreases in Hg concentration apparently were offset by increases in precipitation.

► Data from 5 Hg and precipitation networks in the USA and Canada were combined for the first time.
► High-resolution maps and statistical trends tests were used for spatial and temporal data analysis.
► Some 7-year mean annual Hg concentrations exceeded a 12 ng per liter water-quality criterion.
► Small, localized decreases in Hg concentration were offset by increases in precipitation.
► Hg wet deposition was unchanged in the Great Lakes region and its subregions during 2002–2008.