Monitoring atmospheric levels and deposition of dioxin-like pollutants in sub-alpine Northern Italy

The objective of this work was to assess the atmospheric occurrence, seasonal variations and deposition of dioxin-like pollutants (17 PCDD/Fs + 12 DL-PCBs) in sub-alpine northern Italy. A total of 108 weekly integrated samples (aerosol + gas phases) were collected during a 1-year period (2005–2006) at the Ispra EMEP site (Northern Italy, 45°49′N, 8°38′E). Atmospheric loadings into Lake Maggiore were also estimated by implementing a deposition model. ∑2,3,7,8-PCDD/F atmospheric total concentrations were dominated by the aerosol-bound fraction which ranged from 50 to 3080 (1–215 WHO98 TEQ) fg m−3. In contrast DL-PCB levels were dominated by the gas phase concentrations and varied from 1800 to 14800 (1–5 WHO98 TEQ) fg m−3. The aerosol and gas phase concentrations of PCDD/Fs and DL-PCBs exhibited a similar seasonality (higher values in winter time for aerosol-bound contaminants and lower concentrations for gas phase contaminants) in spite of their different environmental sources and properties. Estimated total atmospheric (dry + wet) depositional fluxes of dioxin-like pollutants in sub-alpine northern Italy were ∼0.2–∼9.5 ng m−2 d−1, with wet deposition dominating. Total atmospheric inputs (2,3,7,8-PCDD/Fs + DL-PCBs) into Lake Maggiore ranged from 14 to 304 g y−1. Higher environmental concentrations of dioxin-like pollutants in sub-alpine northern Italy are expected in the cold season and in rainy days due to a combined effect of stagnant atmospheric conditions (low winds), household wood burning in the region and higher pollutant loads via rainfall in winter.

Figure optionsDownload high-quality image (327 K)Download as PowerPoint slideHighlights
► PCDD/F levels are in the range of those in rural/semi-rural areas world-wide.
► DL-PCB levels are in the range of those in moderate urban/industrial impacted areas.
► Contaminant burden in winter precipitation events is higher than in summer rains.
► Up to 300 g of PCDD/F + DL-PCB can be deposited into Lake Maggiore waters yearly.