کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4441547 | 1311112 | 2009 | 11 صفحه PDF | دانلود رایگان |
More than 2500 measurements of C2–C8 non-methane hydrocarbons (NMHCs) have been conducted at Finokalia sampling station on the island of Crete over a thirty-month period (September 2003–February 2006), to investigate the factors controlling NMHC levels and estimate their role in the oxidizing capacity of the Eastern Mediterranean atmosphere. Atmospheric concentrations of NMHCs range from below the detection limit (5 pptv) to a few ppbv and present a hydroxyl radical (OH) driven seasonal pattern with lower values during summer. The diel variability was also influenced by the reaction of the NMHC with the OH radical, exhibiting a nighttime maximum and a midday or early afternoon minimum. Long-lived compounds demonstrate higher concentrations under the influence of the northern sector (European continent), indicating that besides chemistry, transport significantly contributes to NMHCs levels in the area. Based on the observed NMHCs diurnal cycles, mean OH radical levels of 3.5 × 106 molecules cm−3 have been derived for May–October period.
Journal: Atmospheric Environment - Volume 43, Issue 35, November 2009, Pages 5611–5621