کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4441955 | 1311130 | 2009 | 7 صفحه PDF | دانلود رایگان |

Current regional models for predicting atmospheric organic particulate matter (OPM) levels rely heavily on the computationally simple, lumped “two-product” (2p) approach for parameterizing the formation of secondary organic aerosol (SOA). At the other extreme, molecular kinetic models of SOA formation are available that use numerous complex reaction pathways to produce large numbers of potentially condensable organic oxidation products, but the complexities of those models currently limit implementation in large-scale air quality models. This study proposes use of a carbon number (nC) vs. polarity grid (with concentration bins) for tracking the various OPM-relevant compounds and their time-dependent concentrations TiTi (μg m−3). The grid can be used when adding complexity to the 2p approach, or for managing and limiting the complexity of molecular kinetic models. For the former, an expanded np+mPnp+mP approach is proposed with n products and m possible types of very low volatility polymer (P)(P) materials. For the latter, the grid limits system complexity by allowing compounds with similar structures to be lumped together in the same grid bin even when they are formed by different routes. With either an np+mPnp+mP approach or a molecular kinetic approach, the nC vs. polarity grid will allow consideration of the effects of variation in the activity coefficients ζi of the partitioning compounds, variation in the mean molecular weight of the absorbing OPM phase, water uptake, and the possibility of phase separation in the OPM phase.
Journal: Atmospheric Environment - Volume 43, Issue 17, June 2009, Pages 2829–2835