Carbon cycling across the southern margin of Laurentia during the Late Ordovician

• The GICE is recorded in northeastern Alabama as a 1.5‰ positive excursion.
• Increasing δ13C values supports a 13C enrichment of the global carbon reservoir.
• Alabama δ13C trends correlate with compilations of North American chemostratigraphy.
• There is no evidence of sea level control on δ13C trends.
• There is no evidence of δ13CDIC gradients at the margin of Laurentia's epeiric sea.

The Guttenberg Isotope Carbon Excursion (GICE), a positive carbon isotope excursion that occurs near the base of the Katian Stage, is thought to be a global event possibly related to Late Ordovician cooling. Documenting how much regional and global variability exists in carbon isotopic trends prior to and during the GICE is a critical aspect in understanding the implications of the excursion for interpreting changes in the global carbon cycle, paleoclimate, and chemostratigraphic correlation during the Ordovician. To investigate carbon isotopic trends along the southern margin of the Laurentian carbonate platform during the Late Ordovician, we measured bulk carbonate δ13Ccarb and δ18Ocarb as well as organic carbon δ13Corg values from four locations in Alabama. These sections are excellent study sites because they are well exposed, contain the regionally well-correlated Deicke and Millbrig K-bentonites, and are in a region where δ13C trends have not been studied.Carbonate δ13Ccarb results from one section (i.e. Fort Payne) in northeastern Alabama record a 1.5‰ positive excursion above the Millbrig K-bentonite. We interpret the 1.5‰ positive excursion as a primary feature and identify it as the GICE. The characteristic GICE excursion is absent in the other study sections and we attribute this absence to the presence of unconformities (either non-depositional or erosional) in these sections. We find neither evidence for sea level control on δ13C trends nor conclusive evidence for δ13CDIC gradients along the southeast margin of Laurentia's epeiric sea. Combined with the proximity to the Iapetus Ocean, these results suggest that carbon isotopic trends in Alabama are a reliable proxy for open ocean conditions. Therefore, despite the absence of GICE excursion in all but one of our study sections, increasing δ13C values in Alabama prior to the GICE provides evidence for a steady 13C enrichment of the global surficial carbon reservoir consistent with a drawdown of atmospheric CO2 during the early Late Ordovician