Controlling factors on heavy mineral assemblages in Chinese loess and Red Clay

• First QEMSCAN-based heavy mineral study of Chinese loess and Red Clay
• No provenance shifts for Chinese loess during at least the past 500 kyr
• Climate control of heavy mineral assemblages of Chinese loess before ~ 1 Ma
• Similar provenances for bottom Red Clay and loess deposited during the past 500 kyr
• QEMSCAN and optical heavy mineral counting techniques have consistent patterns.

Heavy-mineral analysis is a sensitive technique in constraining provenance of sandstone, but has rarely been applied to loess. Here we report a heavy-mineral study of selected samples from the Luochuan, Xifeng and Caoxian loess-Red Clay sections on the Chinese Loess Plateau, based on the novel QEMSCAN (Quantitative Evaluation of Minerals by Scanning Electron Microscopy) technique. We found that heavy mineral assemblages of loess deposited through the past 500 kyr are similar and unchanged by post-depositional chemical dissolution. In contrast, in samples deposited from 900 ka to 3 Ma, the relative proportion of stable minerals tends to increase down section. In addition, the Xifeng samples consistently display higher contents of unstable ferromagnesian minerals than the Luochuan samples. Detailed analysis of surface textures displayed by different minerals by optical methods indicates that such a compositional difference can be ascribed to more effective diagenetic dissolution for the Luochuan section, explained by more extensive percolation of interstitial waters in wetter climatic conditions. Interestingly, heavy-mineral assemblages in the underlying upper Miocene Red Clay from Xifeng (deposition age ~ 7 Ma) are similar to those of recent loess deposited since 500 ka. This similarity indicates that climate and/or local preservation conditions hampered dissolution reactions, thus helping to preserve an original provenance signal that remained largely unchanged throughout the considered time period. Our study demonstrates that climatically- and time-controlled diagenesis plays a key role in determining the composition of heavy-mineral assemblages contained in loess deposited several hundreds of thousands years ago. We also show that by using both QEMSCAN and traditional optical techniques on the same samples we can obtain fundamental complementary information for a correct interpretation of the heavy-mineral assemblage.