Al2O3/TiO2 ratio of the clay fraction of Late Ordovician–Silurian carbonate rocks as an indicator of paleoclimate of the Fennoscandian Shield

In the Fennoscandian Shield the fluctuations in arid–humid climate conditions are inferred from the Al2O3/TiO2 ratio of the clay fraction of Estonian carbonate rocks of the Baltoscandian sedimentary Basin. The Late Ordovician climate of the Fennoscandian Shield was mainly semi-humid with several humid pulses in the Sandbian, mid-Katian and Hirnantian. The post-Hirnantian climate was fluctuating between humid and arid until stable humid conditions were established in the Middle and early Late Llandovery. Starting from the latest Llandovery, the climate turned semi-arid and arid. The Ordovician–Silurian long-term trend toward aridity was caused by the equator-ward drift of the Baltica plate. Shorter-term fluctuations of Al2O3/TiO2 reflect climate changes of the global extent.

► The Al/Ti of clay fraction reflects climate of the provenance.
► Increasing trend of Al/Ti ratio corresponds to Baltica drift equatorward.
► Al/Ti excursions show global and regional climatic changes.