Utilization of municipal solid waste incineration fly ash for sulfoaluminate cement clinker production

The feasibility of partially substituting raw materials with municipal solid waste incineration (MSWI) fly ash in sulfoaluminate cement (SAC) clinker production was investigated by X-ray diffraction (XRD), compressive strength and free expansion ratio testing. Three different leaching tests were used to assess the environmental impact of the produced material. Experimental results show that the replacement of MSWI fly ash could be taken up to 30% in the raw mixes. The good quality SAC clinkers are obtained by controlling the compositional parameters at alkalinity modulus (Cm) around 1.05, alumina–sulfur ratio (P) around 2.5, alumina–silica ratio (N) around 2.0∼3.0 and firing the raw mixes at 1250 °C for 2 h. The compressive strengths of SAC are high in early age while that develop slowly in later age. Results also show that the expansive properties of SAC are strongly depended on the gypsum content. Leaching studies of toxic elements in the hydrated SAC-based system reveal that all the investigated elements are well bounded in the clinker minerals or immobilized by the hydration products. Although some limited positive results indicate that the SAC prepared from MSWI fly ash would present no immediate thread to the environment, the long-term toxicity leaching behavior needs to be further studied.

► The replacement can be taken up to 30% of MSWI fly ash in the raw mix.
► The novelty compositional parameters were defined, their optimum values were determined.
► Expansive property of SAC is strongly depended on gypsum content.
► Three leaching test methods are used to assess the environmental impact.