Insulation rigid and elastic foams based on albumin

Albumin-based rigid and elastic foams were prepared by mechanically beating water solutions of the protein mixed with formaldehyde and camphor. The resulting foams were cross-linked in a traditional or in a microwave oven. Formaldehyde was used as hardener of the protein and camphor as a plasticizer. Thermal conductivity was tested and found to be acceptable for thermal insulation but did not appear to be influenced by variations in foam density. Scanning electron microscopy of the different formulations showed some differences in cells structure. Formulations of different water content, formaldehyde hardener content, camphor content and oven curing time were tested. Within certain limits (a) increases in water proportion rendered the foam more elastic, (b) higher formaldehyde content increased foam rigidity and strength up to a value beyond which no further increase occurred, (c) the amount of camphor influences markedly the compression strength and foam elasticity/plasticity, (d) curing time improving foam strength up to 5 min in microwave curing, without any further effect for longer heating times. Only addition of glycerol, yielded truly soft elastic foams.

► Albumin-based rigid and elastic foams were prepared.
► Formaldehyde was used as hardener of the protein and camphor as a plasticizer.
► Thermal conductivity was acceptable for thermal insulation.
► Thermal conductivity was not influenced by variations in foam density.
► Addition of glycerol yielded soft elastic foams.