Geochemical evolution of Ngorongoro Caldera, Northern Tanzania: Implications for crust–magma interaction

Ngorongoro Caldera is the largest and best-preserved of nine Plio-Pleistocene volcanoes that make-up the Ngorongoro Volcanic Highlands (NVH) complex situated at the southern bifurcation of Gregory Rift, part of the East African Rift system of northern Tanzania. We report here, major and trace element abundances, Sr–Nd–Pb isotope analyses and 40Ar/39Ar laser incremental-heating and total fusion ages on lava and tephra sampled from stratigraphic sections exposed within the Ngorongoro Caldera.Major and trace elements measured on samples collected from the Ngorongoro Caldera wall indicate a stratified magma chamber whose silicic top and basaltic bottom was inverted by sequential eruptions. Samples from the lower part of the exposed Ngorongoro Caldera wall are high in silica, alkalis and HFSE (High Field Strength Elements). The Zr, Nb and Hf concentrations are highly correlated with each other and decrease up-section, indicative of the extent of magma evolution. Modeling of major, trace as well as Sr, Nd and Pb isotope data suggests that assimilation fractional crystallization processes were essential in producing the observed geochemical variations.The Sr and Nd isotope ratios from the Ngorongoro samples are widely dispersed (87Sr/86Sr = 0.70405 to 0.70801, 143Nd/144Nd = 0.512205 to 0.512623) and Pb isotope ratios are consistent with previous studies: 206Pb/204Pb = 18.73 to 19.37, 207Pb/204Pb = 15.64 to 15.69, 208Pb/204Pb = 39.52 to 39.55. Although Sr isotopic ratios are similar to Oceanic Island Basalt (OIB), the more radiogenic samples (87Sr/86Sr > 0.705) from the lower part of the section suggest crust–magma interaction; this is supported by Ce/Pb ratios (< 25 ± 5) which are lower than those expected from primary mantle derived fluids. Moderate normalized Tb/Yb ratios (2.7–2.1) of these samples suggest lithospheric mantle melting, a finding consistent with other studies in the region.Laser incremental-heating of basalt samples and single grain total fusion of anorthoclase from tephra samples collected from the Ngorongoro Caldera wall section yield 40Ar/39Ar ages of 2.25 ± 0.02 Ma to 2.01 ± 0.02 Ma, constraining a duration of volcanism of the order of ~ 240 kyr. These ages suggest correlation of a normal to reverse geomagnetic polarity transition measured in the Ngorongoro Caldera wall section with the ~ 2.14 Ma C2r.1n–1r (normal to reverse) Réunion–Matuyama boundary.