High-temperature annealing of amoeboid olivine aggregates: Heating experiments on olivine–anorthite mixtures

Amoeboid olivine aggregates (AOAs) are composed of forsteritic olivine, Fe,Ni-metal, and Ca,Al-rich nodules consisting mainly of Al-diopside, spinel, and anorthite. Although the textures, shapes, and mineralogy of AOAs are consistent with their being aggregates of nebular condensates, some textures are in conflict with equilibrium condensation calculations, indicating that AOAs were not produced by a simple one-stage condensation. To examine the origin of the constituent minerals within AOAs and their textural relationships, we performed heating experiments using mineral mixtures analogous to those in AOAs. Isothermal and cooling experiments on forsterite + anorthite mixtures reveal that a high-Ca pyroxene phase forms via the incipient melting of the two minerals. Comparative studies of heating experiments performed using the mineralogy of AOAs suggest that Al-diopside in AOAs can be produced from a small degree of melting of forsterite and anorthite. The formation of Al-diopside in this way is consistent with the annealing textures observed in AOAs, and it may account for the discrepancy between the observed mineralogy of AOAs and the results of equilibrium condensation calculations, the occurrence of two types of diopside (Al,Ti-rich diopside and Al-diopside), and the variable Al2O3 content of Al-diopside.