کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4741933 | 1641543 | 2011 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Melting and thermal pressure of hcp-Fe from the phonon density of states Melting and thermal pressure of hcp-Fe from the phonon density of states](/preview/png/4741933.png)
We directly probed the phonon density of states (DOS) of hexagonal close-packed iron (ε-Fe) with high statistical quality between pressures of 30 GPa and 151 GPa using nuclear resonant inelastic X-ray scattering and insitu synchrotron X-ray diffraction experiments at 300 K. From each measured phonon DOS, we determined the vibrational free energy (Fvib) and mean-square displacement of atoms, 〈u2〉. The volume dependence of Fvib is directly related to the vibrational thermal pressure, which we combine with previously reported theoretical values for the electronic and anharmonic thermal pressures to find the total thermal pressure (Pth). In addition, we obtained the shape of ε-Fe’s melting curve from the volume dependence of our 〈u2〉, and anchored it with an experimentally determined melting point to obtain the high-pressure melting behavior of ε-Fe. Considering thermal pressure and anharmonic effects, we found ε-Fe’s melting temperature at the pressure of Earth’s core–mantle boundary (P = 135 GPa) to be 3500 ± 100 K. Extrapolating our melting curve to the pressure of the inner-core boundary (ICB, P = 330 GPa), where Earth’s solid inner-core and liquid outer-core are in contact, we determined a melting temperature for ε-Fe of 5600 ± 200 K. Finally, combining this temperature constraint with our Pth, we determined the density of ε-Fe under ICB conditions to be 13.50 ± 0.03 g/cm3, which is 5.5 ± 0.2% higher than the seismically inferred density at the ICB.
► Most accurate-to-date volume-dependent phonon DOS of iron up to 151 GPa at 300 K.
► Vibrational thermal pressure in outer core from volume-dependence of phonon DOS.
► High-P melting behavior of ε-Fe from experiments at 300 K and anchor melting point.
► TM(135 GPa) = 3500 ± 100 K and TM(330 GPa) = 5600 ± 200 K, including Pth and anharmonicity.
► Pth and TM at inner-core boundary give a core density deficit of 5.5 ± 0.2%.
Journal: Physics of the Earth and Planetary Interiors - Volume 188, Issues 1–2, September 2011, Pages 114–120