کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4756455 1419014 2017 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective production of carvacrol from carvone over supported Pd catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Selective production of carvacrol from carvone over supported Pd catalysts
چکیده انگلیسی
The selective conversion of biomass-derived carvone in H2 was studied over (Al2O3, C and CeO2) supported Pd (mean size 2.8-3.0 nm), taking bulk Pd as benchmark. 100% carvacrol yield was achieved over Pd/Al2O3, Pd/C and bulk Pd at an inlet H2/carvone = 1/6, with appreciably higher rates for the supported catalysts. Carveol formation over Pd/CeO2 was attributed to CO activation at surface oxygen vacancies (confirmed by O2 titration) generated during TPR. Carvotanacetone and carvomenthone formation were observed at H2/carvone > 1/6.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 96, June 2017, Pages 37-40
نویسندگان
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