کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4757300 | 1361634 | 2017 | 5 صفحه PDF | دانلود رایگان |
- MoVTeNb oxides catalyze oxidation, oxidative esterification and ammoxidation of acrolein.
- A common mechanism for these reactions is suggested.
- Acrylic species can be initially formed as a result of the oxidation stage.
- These species undergo nucleophilic substitution with water, alcohols or ammonia.
- As a result, acrylic acid, its esters and acrylonitrile are produced, respectively.
It is known that nucleophilic acyl substitution in the RCOX compounds with “good leaving” groups X is a fundamental and energetically favorable route to carboxylic acid derivatives. When water, alcohols and ammonia are used as nucleophiles, carboxylic acids, esters and amides (or nitriles) are obtained, respectively. On the other hand, the same products are derived from aldehydes upon their catalytic aerobic oxidation, on condition that water, alcohols and ammonia are present in the feed gas. Therefore, one can surmise that nucleophilic substitution reactions are involved intrinsically in the catalytic oxidation reactions. In agreement with this hypothesis we have shown, as an example, that the selfsame catalyst, MoVTeNb mixed oxides, enables successful oxidation, oxidative esterification and ammoxidation of acrolein. The mechanistic aspects of these reactions are considered based on established organic and general chemistry principles.
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Journal: Catalysis Today - Volume 279, Part 1, 1 January 2017, Pages 90-94