کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
49308 | 46733 | 2015 | 4 صفحه PDF | دانلود رایگان |
• Oxidation of N-phosphonomethyl iminodiacetic acid by H2O2 at 70 °C to its N-oxide in a two-phase system was investigated.
N-phosphonomethyl iminodiacetic acid (PMIDAA) was oxidized in a two phase liquid system by 32% hydrogen peroxide at 70 °С. Reaction was performed in the presence of tungsten oxo- and peroxo- complexes, containing N-hexadecylpyridinium or quaternary ammonium cation. Substrate conversion and N-oxide PMIDAA selectivity were found to depend on anions structure and quaternary nitrogen containing cation properties. The best results were obtained when PMIDAA was oxidized in the presence of N-hexadecylpyridinium tetra(oxodiperoxotungsto)phosphate, substrate conversion being 99%, and target product selectivity being 97%.
Figure optionsDownload as PowerPoint slide
Journal: Catalysis Communications - Volume 71, 5 November 2015, Pages 102–105