کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
49615 46756 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Debenzylation of vanillic acid over sulfosuccinic acid functionalized mesoporous silica nanocomposites
ترجمه فارسی عنوان
دباسیلی کردن اسید وانیلیک بر روی نانو کامپوزیت سیلیکا مسیپوروس
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• Sulfosuccinic acid functionalized ordered mesoporous silica was synthesized and characterized for the first time.
• Liquid phase debenzylation of vanillic acid showed very high selectivity of the product.
• Plausible reaction mechanism was explained.

Sulfosuccinic acid functionalized mesoporous silica (SBA/SSA) was synthesized and characterized for debenzylation of vanillic acid in liquid phase for the first time. The catalytic activity studies showed high activity (82%) and selectivity (96%) for the desired product vanillic acid over SBA/SSA compared to 74% selectivity over silica/SSA. Synergistic effects of acidic/basic groups responsible for higher activity and selectivity were explained with plausible mechanism.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 51, 5 June 2014, Pages 90–94
نویسندگان
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