کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4995956 | 1459432 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On some corrections to paper 'CaO solubility and activity coefficient in molten salts CaCl2-x (x = 0, NaCl, KCl, SrCl2, BaCl2 and LiCl)' published in Thermochim. Acta, 2008, V. 470, No 1-2, pp. 105-107
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: On some corrections to paper 'CaO solubility and activity coefficient in molten salts CaCl2-x (x = 0, NaCl, KCl, SrCl2, BaCl2 and LiCl)' published in Thermochim. Acta, 2008, V. 470, No 1-2, pp. 105-107 On some corrections to paper 'CaO solubility and activity coefficient in molten salts CaCl2-x (x = 0, NaCl, KCl, SrCl2, BaCl2 and LiCl)' published in Thermochim. Acta, 2008, V. 470, No 1-2, pp. 105-107](/preview/png/4995956.png)
چکیده انگلیسی
Imperfections in the treatment of the experimental results (calculation of the activity coefficients) on CaO behavior in melts of CaCl2-x (x = 0, NaCl, KCl, SrCl2, BaCl2 and LiCl) compositions used in the above-mentioned paper caused their incorrectness. A primitive variant of isothermal saturation resulted in the overestimation of CaO solubility in the studied melts by, at least, 20%. Nevertheless, negative deviations from the ideality caused by strong interaction between CaO and CaCl2 (formation of compounds) were found. The strengthening of oxoacidic properties of constituent cations leads to increase of CaO solubility in the studied melts.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 654, 10 August 2017, Pages 51-53
Journal: Thermochimica Acta - Volume 654, 10 August 2017, Pages 51-53
نویسندگان
Victor L. Cherginets, Tatyana P. Rebrova,