کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
50232 46785 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Au@Pt core-shell nanoparticles supported on multiwalled carbon nanotubes for methanol oxidation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Au@Pt core-shell nanoparticles supported on multiwalled carbon nanotubes for methanol oxidation
چکیده انگلیسی

Au@Pt core-shell nanoparticles were synthesized by a simple one-step ultraviolet irradiation method and were then assembled on functionalized multiwalled carbon nanotubes (MWCNTs) surface. This new type of Au@Pt/MWCNTs composite catalysts was characterized by UV–vis spectrometry, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning TEM, HRTEM, and electrochemical techniques. The results revealed that the Au@Pt nanoparticles with an average diameter less than 5 nm were well coated on the MWCNTs surface. As compared with commercial Pt/C catalysts, the Au@Pt/MWCNTs prepared using Au/Pt atomic ratio of 1:1 exhibited distinctly higher activity and better stability toward methanol oxidation in alkaline media.

Figure optionsDownload as PowerPoint slideResearch highlights
► Au@Pt nanoparticles were synthesized by a simple one-step ultraviolet irradiation.
► Au@Pt nanoparticles were assembled on MWCNTs surface with well dispersion.
► Au@Pt/MWCNTs showed the excellent catalytic performance for methanol oxidation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 13, Issue 1, 5 October 2011, Pages 54–58
نویسندگان
, , , , , ,