کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
50761 46812 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of high-surface-area micro/mesoporous ZnAl2O4 catalyst support and application in selective hydrogenation of o-chloronitrobenzene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Synthesis of high-surface-area micro/mesoporous ZnAl2O4 catalyst support and application in selective hydrogenation of o-chloronitrobenzene
چکیده انگلیسی

High-surface-area ZnAl2O4 with micro/mesoporous frameworks was synthesized via a facile one-pot solvothermal approach without using any surfactants or post-treatment. The results revealed that the textural properties of micro/mesoporous ZnAl2O4 were tuned by changing alcohol/water mixture solvents used in solvothermal synthesis and Ag nanoparticles were dispersed uniformly on the surface of ZnAl2O4 supports. Especially, the supported Ag catalyst on the microporous ZnAl2O4 synthesized in methanol/water solvent exhibited good catalytic performance for liquid phase selective hydrogenation of o-chloronitrobenzene to o-chloroaniline, owing to the high dispersion of Ag nanoparticles and the strong metal-support interaction.


► Micro/mesoporous ZnAl2O4 was fabricated via one-pot solvothermal approach.
► The textural properties of ZnAl2O4 were tuned by changing alcohol/water solvents.
► Ag nanoparticles could be dispersed uniformly and stably on the ZnAl2O4 supports.
► Supported catalysts exhibited good catalytic performance in selective hydrogenation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 15, Issue 1, 15 November 2011, Pages 113–117
نویسندگان
, , ,