کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51187 | 46834 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Asymmetric oxidation of sulfides with hydrogen peroxide catalyzed by a vanadium complex of a new chiral NOO-ligand
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Asymmetric oxidation of sulfides with hydrogen peroxide catalyzed by a vanadium complex of a new chiral NOO-ligand Asymmetric oxidation of sulfides with hydrogen peroxide catalyzed by a vanadium complex of a new chiral NOO-ligand](/preview/png/51187.png)
چکیده انگلیسی
A new chiral NOO-tridentate ligand (8R)-2-(2-hydroxyphenyl)-4-methyl-5,6,7,8-tetrahydro-quinolin-8-ol (1) bearing a rigid tetrahydroquinoline framework was prepared and applied in the vanadium-catalyzed asymmetric oxidation of aryl methyl sulfides with H2O2 as oxidant. Less toxic acetone was found to be the proper solvent for the enantioselective oxidation of sulfides. Under the optimal condition, the asymmetric oxidation of aryl methyl sulfides in acetone catalyzed by VO(acac)2/1 at 0 °C gives good to high yields (80–95%) of sulfoxides with enantioselectivity up to 77% ee.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 11, Issue 4, 15 December 2009, Pages 294–297
Journal: Catalysis Communications - Volume 11, Issue 4, 15 December 2009, Pages 294–297
نویسندگان
Haibin Liu, Mei Wang, Yu Wang, Ying Wang, Hui Sun, Licheng Sun,