کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
51203 46835 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oxidation of alkylaromatics to benzylic ketones using TBHP as an oxidant over LaMO3 (M = Cr, Co, Fe, Mn, Ni) perovskites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Oxidation of alkylaromatics to benzylic ketones using TBHP as an oxidant over LaMO3 (M = Cr, Co, Fe, Mn, Ni) perovskites
چکیده انگلیسی

A series of LaMO3 (M = Cr, Co, Fe, Mn, Ni) perovskites were synthesized by citrate precursor decomposition method and characterized by XRD technique. The catalytic activity of the synthesized perovskites was investigated for the oxidative functionalization of alkylaromatics to benzylic ketones using TBHP as an oxidant. Of various perovskites screened, LaCrO3 exhibited remarkable catalytic activity providing the oxidation of alkylarenes selectively at the benzylic position. The LaCrO3/TBHP catalytic system provides excellent yields of the desired ketones under solvent-free conditions and the catalyst can be successfully used up to six consecutive cycles with no significant loss in activity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 15, 15 September 2009, Pages 2004–2007
نویسندگان
, ,