Magnetic nanoparticles coated by acidic functionalized poly(amidoamine) dendrimer: Effective acidic organocatalyst

A novel magnetic BrØnsted acid catalyst was synthesized based on growing poly(amidoamine) dendrimers on the surface of magnetic nanoparticles. After the dendronizing process, the MNP coated PAMAM was functionalized by chlorosulfuric acid to form an acid catalyst. Because of dendrimer coating of MNPs, catalyst shows good loading level of acidic groups on the surface. Also zwitterion nature of catalyst surface improves the catalytic activity. This new catalyst is proven to be highly effective in the synthesis of α-aminophosphonate compounds in a green way.

► A dendrimer coated magnetic organocatalyst was synthesized.
► Polyamidoamine dendrimer was grown on the surface of MNP.
► Catalyst shows high activity due to zwitterion structure.
► The synthesized catalyst was applied for the synthesis of α-aminophosphonate.
► Catalyst was recycled seven times without significant loss of activity.