Monitoring changes in acid value, total polar material, and antioxidant capacity of oils used for frying chicken

- Discarding points of frying oils were determined using TPM and DPPH methods.
- High correlations of TPMs were observed by column chromatography and a Testo™ 270.
- A decrease of DPPH in isooctane was due to the formation of TPMs in frying oils.
- Oxidized oils with above 24% TPM could be predicted using a DPPH method.

Oxidation products and tocol homologues were monitored in oils during chicken frying to determine the discarding point of highly used frying oils. Oils were heated without chicken for 170 h while chicken frying was performed 130 cycles at 180 °C. As heating time and frying cycles increased, all oxidation parameters including acid value, total polar materials (TPM), conjugated dienoic acid (CDA), and p-anisidine values (p-AV) increased significantly (p < 0.05). γ-Tocopherol and γ-tocotrienol had the lowest stability in oils during heating or frying processes compared to other tocol homologues. TPM values over 24% were obtained after about 109 h for heated oil and 100 cycles for oils used to fry chicken. A decrease of 2,2-diphenyl-1-picrylhydrazyl (DPPH) in isooctane and methanol was highly correlated with the formation of TPM in oils during the frying process. Both DPPH loss and TPM values could be applied to determine the discarding points of highly used frying oils.