کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51409 | 46842 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nickel complexes bearing 2-(1H-benzo[d]imidazol-2-yl)-N-benzylidenequinolin-8-amines: Synthesis, structure and catalytic ethylene oligomerization
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
A series of 2-(1H-benzo[d]imidazol-2-yl)-N-benzylidenequinolin-8-amines was synthesized and characterized. They are stable as solids while displaying a tendency to decompose in solution. On reaction with NiCl2, different coordination pattern sets of L·NiCl2 or [L2Ni]2+·2Cl− are obtainable in THF or ethanol. When activated by Et2AlCl, the complexes L·NiCl2 exhibit good to high catalytic activities and selectivities for 1-C4 in ethylene oligomerization, while the complexes [L2Ni]2+·2Cl− hardly showed any activity, which is attributable to nickel coordination by two ligands barring interaction of ethylene with the metal center.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 13, 25 July 2009, Pages 1730–1733
Journal: Catalysis Communications - Volume 10, Issue 13, 25 July 2009, Pages 1730–1733
نویسندگان
Kefeng Wang, Rong Gao, Xiang Hao, Wen-Hua Sun,