کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5144790 1496868 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of ultrasound-assisted extraction on the pyrolysis characteristics and kinetic parameters of eucalyptus
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Influence of ultrasound-assisted extraction on the pyrolysis characteristics and kinetic parameters of eucalyptus
چکیده انگلیسی
In this study, the influence of ultrasound-assisted extraction on eucalyptus samples with special focus on pyrolysis characteristics and kinetic parameters was explored. Ultrasound and Soxhlet extraction were used to pretreat samples respectively, then samples were assayed by component analysis, TG-FTIR, and kinetic analysis. Ultrasound-assisted extraction did change the physiochemical characteristics of eucalyptus samples, particularly in regards to the quantity of extractives obtained. In TG and DTG curves, ultrasound-extracted samples reflected lower residual weight ratio (17.77%) and higher maximum weight loss rate (−22.92%/min), and were accompanied by a slight shift in the weight loss rate peak to lower temperature (366 °C). The volatiles produced during pyrolysis and the discrepancies of product distribution between experimental and controlled groups were explored based on TG-FTIR spectra. According to kinetic analysis results, ultrasound-treated samples showed higher activation energy at the primary portion of thermal degradation with an average of 206.09 kJ/mol.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ultrasonics Sonochemistry - Volume 37, July 2017, Pages 47-55
نویسندگان
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